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Lambert, a longtime animal rights campaigner, began performing her Cause for the Paws shows in 2008 to raise funds for the Humane Society.
Kellie Pickler's new album, 100 Proof, made its debut at number-two.
Each book will have a donation plate on the inside cover declaring: 'A Gift to the Children of Nashville from Taylor Swift and Scholastic Inc.'.
Clyde "Bo" Raymond Pickler, Jr. spent much of his daughter's childhood behind bars for various crimes, including a three-year stint in prison for aggravated battery and assault.
Taylor Swift was rumored to have scored the role of Éponine in the upcoming film.
The country singer was devastated to learn about the six-year-old, who suffers from septo-optic dysplasia and was told a week before Christmas she will lose her vision.
Lambert, who also lost her father-in-law earlier this month, expressed her sadness over his death on Twitter.
Big shakeup behind the scenes of Simon Cowell's singing competition
In a statement, released to People.com, the happy couple says, "We are so thankful to have found each other and now be able to spend the rest of our lives together."
Urban was named Male Artist of the Year at the ceremony Sunday night.